Defined metalmethyl compounds were first reported in the middle of the 19th century and the interest in metal alkyls is still growing. So far 26 out of 60 non-r

Bis(phosphinimino)methanide rare earth metal bisborohydrides, as illustrated in Scheme I, were successfully synthesized by salt metathesis reactions of [K{CH(PP

Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first si

This dissertation describes the synthesis, characterization, and reactivity of organometallic complexes of yttrium and the lanthanides in an effort to more comp

The work presented in this thesis discusses the formation and behaviour of a variety of different ArForm rare-earth complexes using five ArForm ligands of varie